1967 Spider-Man Never Step on A Scorpion

Spider-Man TV Series 1967–1970 Paul Soles in Spider-Man (1967) Original cartoon series based on the web-slinging Marvel comic book character, Peter Parker, who, after being bit by a radioactive spider, assumes extraordinary powers.
Creators Steve Ditko, Stan Lee
Stars Paul Kligman, Paul Soles, Peg Dixon
S1.E5 Never Step on a Scorpion Episode aired Oct 7, 1967
Carl Banas in Spider-Man (1967)
The Scorpion, a super-human creation designed to vanquish Spider-Man, has a lethal sting in his tail and he's ready to sting J. Jonah Jameson.
Directors: Clyde Geronimi, Sid Marcus, Grant Simmons
Writers: Phil Babet, Al Bertino, Lin Carter
Stars: Bernard Cowan, Paul Kligman, Paul Soles